We present and analyze briefly partial valence and conduction band sta
tes distributions of Al6Mn and both crystalline and quasicrystalline A
lCuFe phases of dose nominal composition. Low densities of states and
a pseudogap are found at the Fermi energy. We discuss the formation of
this pseudo-gap as due to the diffraction of electronic conduction st
ates by Bragg planes and emphasize its consequences for the densities
of d states of the transition element. We discuss also briefly the tra
nsport properties of some systems like AlCuFe which show the proximity
of a metal-insulator transition.