Anomalous photovoltage in polycrystalline Cd0.25Zn0.75Te thin films ha
s been studied. The effect is described as a combined effect of mainly
p-p(+) junctions at the grain boundaries and surface band bending apa
rt from other factors. A new method has been developed to enhance the
photovoltage by placing a fine mesh in front of the substrate during t
he film deposition. This enhancement of photovoltage is explained with
the help of a trap-induced space-charge model.