Auger electron spectroscopy has been applied to determine the near-sur
face composition of thin A/B/A heterostructures. General equations are
established in terms of inelastic mean free path ratios for presumed
layer growth conditions, for an analyser geometry which can be specifi
ed in terms of a sample tilt angle (alpha) and ranges of take-off angl
es (theta, phi). Use of a controlled glancing incidence, in conjunctio
n with RHEED, gives high surface sensitivity. Applications to the tech
nically interesting systems Si/Ge/Si(100) and Fe/Ag/Fe(110) are given;
comparison with experiment is used to infer the growth morphology, ex
tent of surface segregation and interdiffusion.