PLATINUM CLUSTER CRYPTATES - TRAPPING OF MERCURY(0) AND THALLIUM(I)

Authors
HAO LJ VITTAL JJ PUDDEPHATT RJ
Citation
Lj. Hao et al., PLATINUM CLUSTER CRYPTATES - TRAPPING OF MERCURY(0) AND THALLIUM(I), Inorganic chemistry, 35(2), 1996, pp. 269
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
35
Issue
2
Year of publication
1996
Database
ISI
SICI code
0020-1669(1996)35:2<269:PCC-TO>2.0.ZU;2-F
Abstract
The open cluster complex [Pt-6(mu-CO)(6)(mu-dppp)(2)(dppp)(2)], 1, dpp p = Ph(2)P(CH2)(3)PPh(2), can encapsulate mercury(0) or thallium(I) wi th loss of dppp to give the cryptate cluster[Pt-6(mu(6)-M)(mu-CO)(6)(m u-dppp)(3)](n+), 2(M = Hg, n = 0) or 3(M = Tl, n = 1), respectively.