POLYMORPHISM OF ((TOSYLIMINO)IODO)-O-TOLUENE - 2 NEW MODES OF POLYMERIC ASSOCIATION FOR ARINTS

Authors
CICERO RL ZHAO D PROTASIEWICZ JD
Citation
Rl. Cicero et al., POLYMORPHISM OF ((TOSYLIMINO)IODO)-O-TOLUENE - 2 NEW MODES OF POLYMERIC ASSOCIATION FOR ARINTS, Inorganic chemistry, 35(2), 1996, pp. 275
Citations number
43
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
35
Issue
2
Year of publication
1996
Database
ISI
SICI code
0020-1669(1996)35:2<275:PO(-2N>2.0.ZU;2-N
Abstract
Two different polymorphic structures of (tosyliminoiodo)-o-toluene, o- TolylINTs, (1) have been determined. The structure of polymorph A (tri clinic form) reveals a unique infinite ladder type polymer created by parallel single chain polymers of 1 (associated through I ... O linkag es) bridged by weak I ... N interchain associations. The structure of polymorph B (monoclinic form) forms a polymer built of a backbone cont aining I ... O linkages, similar to half of the ladder structure of po lymorph A. These two structures represent intermediate polymeric forms of the two extremes observed for PhINTs and MeslNTs.