SYNTHESIS AND CRYSTAL-STRUCTURE OF A CATIONIC OXO-BRIDGED NITRIDORUTHENIUM(VI) COMPLEX WITH A CHELATING DIAMINE LIGAND HAVING NO ALPHA-CH GROUP

Authors
CHIU WH GUO CX CHEUNG KK CHE CM
Citation
Wh. Chiu et al., SYNTHESIS AND CRYSTAL-STRUCTURE OF A CATIONIC OXO-BRIDGED NITRIDORUTHENIUM(VI) COMPLEX WITH A CHELATING DIAMINE LIGAND HAVING NO ALPHA-CH GROUP, Inorganic chemistry, 35(2), 1996, pp. 540
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
35
Issue
2
Year of publication
1996
Database
ISI
SICI code
0020-1669(1996)35:2<540:SACOAC>2.0.ZU;2-A
Abstract
[(n-Bu)(4)N][RuNCl4] reacts with 2,5-dimethyl-2,5-hexanediamine (L) in acetone to give a cationic dimeric Ru-VI=N complex [(Ru-VI(L)(2)N)(2) (mu-O)]Cl-4 (1). The X-ray crystal structure of 1 . H2O has been deter mined. The structure of 1 shows two Ru=N units bridged by a mu-oxo lig and. The Ru=N and Ru-O bond distances are 1.66(1) and 1.9896(8) Angstr om, respectively.