DINUCLEAR COMPLEXES OF RU AND OS CONTAINING A RIGID BRIDGING LIGAND -PHOTOPHYSICAL PROPERTIES AND PHOTOINDUCED ENERGY-TRANSFER

Authors
DECOLA L BARIGELLETTI F BALZANI V BELSER P VONZELEWSKY A FRANK M VOGTLE F
Citation
L. Decola et al., DINUCLEAR COMPLEXES OF RU AND OS CONTAINING A RIGID BRIDGING LIGAND -PHOTOPHYSICAL PROPERTIES AND PHOTOINDUCED ENERGY-TRANSFER, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 234, 1993, pp. 115-120
Citations number
11
Categorie Soggetti
Crystallography
Journal title
Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals → ACNP
ISSN journal
1058725X
Volume
234
Year of publication
1993
Pages
115 - 120
Database
ISI
SICI code
1058-725X(1993)234:<115:DCORAO>2.0.ZU;2-K
Abstract
The homo- and hetero-nuclear complexes of Ru(II) and Os(II) containing a bis(bipyridine) rigid bridging ligand (A) have been prepared. Their absorption spectra, electrochemical behavior and luminescence propert ies have been investigated. Luminescence intensity and lifetime measur ements indicate that in the mixed-metal complex [(bpy)2RuAOs(bpy)2]4efficient energy transfer takes place from the Ru-based component to t he Os-based one.