S. Alva et al., MODIFICATION OF PROTOPORPHYRIN-IX FOR FORMATION OF STABLE LANGMUIR-BLODGETT-FILMS, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 234, 1993, pp. 377-383
To facilitate formation of homogeneous stable monomolecular films of p
rotoporphyrin (PPIX), phospholipid PE has been attached to propionic a
cid side chains. The modified compound has been characterized using op
tical and NMR spectroscopy. Fluorescence decay measurements indicate t
hat LB films of these molecules exhibit stable and homogeneous structu
res. Moreover, transfer of energy from a molecule belonging to one lay
er to another in the neighboring layer readily takes place.