B. Dorner et al., THE PHASE-DIAGRAM OF RBFECL3 IN A MAGNETIC-FIELD PERPENDICULAR TO THECHAIN DIRECTION, Canadian journal of physics, 73(11-12), 1995, pp. 800-804
The temperature dependence of,the position and line width of antiferro
magnetic Bragg peaks were measured at different applied magnetic field
s up to 1.4 T by means of elastic neutron scattering. Three different
types of temperature dependences were observed that can be attributed
to the commensurate-incommensurate, commensurate-paramagnetic, and inc
ommensurate-paramagnetic phase transitions. Below 0.3 T the transition
goes from commensurate to incommensurate. Between 0.3 and 0.5 T a pha
se boundary was observed, but there is some doubt as to whether the st
ructure at temperatures below this boundary is commensurate. Between 0
.5 and 1.2 T the phase transition goes directly from commensurate to p
aramagnetic at around 2.5 K. For fields higher than 1.3 T and temperat
ures above 1.5 K no commensurate phase could be identified. But above
1.2 T and still at 1.4 T there exists an incommensurate phase. Based o
n these temperature dependences at different magnetic fields, phase bo
undaries in the H-T phase space are proposed and compared with the pha
se diagram obtained by previous susceptibility measurements.