C. Balarew et R. Stefanova, THE DOUBLE SALTS CD(C6H5COO)(2)CENTER-DOT-CDCL2 AND CD(C6H5COO)(2)CENTER-DOT-CDBR2, Crystal research and technology, 31(1), 1996, pp. 99-106
The systems Cd(C6H5COO)(2)-CdCl2-H2O and Cd(C6H5COO)(2)-CdBr2-H2O have
been studied at 25 degrees C. Formation of the double salts Cd(C6H5CO
O)(2) . CdCl2 and Cd(C6H5COO)(2) . CdBr2 (1:1:0) has been established
and their chemical individuality has been confirmed by chemical, X-ray
, and DT-analyses. Proceeding from data on the structure of Cd(C6H5COO
)(2) . 2 H2O and the composition of the 1:1:0 double salts as well as
using Pauling's rules for the most probable spacial disposition of the
ions, the crystal structure type of the double salts obtained are pre
dicted.