Jm. Gomezrodriguez et al., REAL-TIME OBSERVATION OF THE DYNAMICS OF SINGLE PB ATOMS ON SI(111)-(7X7) BY SCANNING-TUNNELING-MICROSCOPY, Physical review letters, 76(5), 1996, pp. 799-802
The very early stages of Pb deposition on Si(111)-(7 x 7) surfaces hav
e been investigated in real time by scanning tunneling microscopy. The
combination of variable temperature scanning with unusual very long p
eriods of imaging time have enabled us to observe that single Pb atoms
are highly mobile within each half (7 x 7) unit cell. Individual jump
s of single atoms between different half cells have been resolved as w
ell as the formation of atom pairs as a result. An activation energy o
f 0.64 +/- 0.07 eV has been measured for the diffusion of single atoms
between different half cells.