SYNTHESIS AND CRYSTAL-STRUCTURE OF 3,6-DIFERROCENYL-1,8-DIPHENYL-4,5-DITHIAOCTANE

Authors
MA CL ZHANG RF WANG DQ YIN BL
Citation
Cl. Ma et al., SYNTHESIS AND CRYSTAL-STRUCTURE OF 3,6-DIFERROCENYL-1,8-DIPHENYL-4,5-DITHIAOCTANE, ACH, models in chemistry, 132(5), 1995, pp. 767-773
Citations number
7
Categorie Soggetti
Chemistry
Journal title
ACH, models in chemistry → ACNP
ISSN journal
12178969
Volume
132
Issue
5
Year of publication
1995
Pages
767 - 773
Database
ISI
SICI code
1217-8969(1995)132:5<767:SACO3>2.0.ZU;2-D
Abstract
The compound C6H5COCH2CH(Fc)SSCH(Fc)CH2COC6H5 is synthesized by the ox idation of 1-phenyl-3-ferrocenyl-1-oxo-3-mercapto-propane which is obt ained from nucleophilic addition of H2S to the 1-ferrocenyl-3-phenyl-3 -oxo-propene. Its crystal structure has been determined by X-ray cryst allography, it crystallizes in the triclinic system, space group <P(1) over bar> with a=11.491(5), b=11.805(5), c=12.510(5)Angstrom, alpha=10 9.00(3), beta=93.90(4), gamma=99.56(4)degrees, V=1568.7 Angstrom(3), a nd Z=2.