THE REACTIONS OF TETRAKIS(TRIPHENYLPHOSPHINE)PLATINUM AND TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM WITH SELENIUM - X-RAY CRYSTAL-STRUCTURE OF [PT(SE2CH2)(PPH(3))(2)]

Authors
KHANNA PK MORLEY CP HURSTHOUSE MB MALIK KMA HOWARTH OW
Citation
Pk. Khanna et al., THE REACTIONS OF TETRAKIS(TRIPHENYLPHOSPHINE)PLATINUM AND TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM WITH SELENIUM - X-RAY CRYSTAL-STRUCTURE OF [PT(SE2CH2)(PPH(3))(2)], Heteroatom chemistry, 6(6), 1995, pp. 519-524
Citations number
19
Categorie Soggetti
Chemistry
Journal title
Heteroatom chemistry → ACNP
ISSN journal
10427163
Volume
6
Issue
6
Year of publication
1995
Pages
519 - 524
Database
ISI
SICI code
1042-7163(1995)6:6<519:TROTAT>2.0.ZU;2-4
Abstract
Treatment of tetrakis (triphenylphosphine)platinum with elemental sele nium (red or vitreous) in toluene solution under reflux yields art ins oluble solid. This dissolves in dichloromethane with reaction, eventua lly to form a 1:1 mixture of [PtCl2(PPh(3))(2)] and the new compound [ Pt(Se2CH2)(PPh(3))(2)], which has been characterized by multinuclear N MR spectroscopy and X-ray crystallography. Under the same conditions, tetrakis(triphenylphosphine)-palladium yields only decomposition produ cts. (C) 1996 John Wiley & Sons, Inc.