ORGANOPHOSPHORUS COMPOUNDS .102. ACID-INDUCED CYCLOTRIMERIZATION OF APHOSPHAALKYNE WITH FORMAL INCORPORATION OF WATER

Authors
MACKEWITZ TW BERGSTRASSER U LEININGER S REGITZ M
Citation
Tw. Mackewitz et al., ORGANOPHOSPHORUS COMPOUNDS .102. ACID-INDUCED CYCLOTRIMERIZATION OF APHOSPHAALKYNE WITH FORMAL INCORPORATION OF WATER, Heteroatom chemistry, 6(6), 1995, pp. 617-621
Citations number
28
Categorie Soggetti
Chemistry
Journal title
Heteroatom chemistry → ACNP
ISSN journal
10427163
Volume
6
Issue
6
Year of publication
1995
Pages
617 - 621
Database
ISI
SICI code
1042-7163(1995)6:6<617:OC.ACO>2.0.ZU;2-2
Abstract
tert-Butylphosphaacetylene 1 can be cyclotrimerized with incorporation of water to furnish the 1,2,4-triphosphabicyclo[2.1.1]hex-2-ene 5 in the presence of trifluoroacetic acid. This novel bicyclic system has b een fully characterized by spectral and analytical data. The constitut ion of 5 has been unambiguously demonstrated by X-ray crystallography. (C) 1996 John Wiley & Sons, Inc.