H. Sasakura et al., SYNTHESIS OF BI-2222 COMPOUNDS NOT CONTAINING TETRAVALENT IONS - BI2SR2-XLA2-YLNX+YCU2OZ (LN = SM, EU, GD AND DY), Physica. C, Superconductivity, 218(3-4), 1993, pp. 495-500
Bi-based cuprate systems with the 2222 structure have been synthesized
without doping of tetravalent ions such as Ce4+ or Pr4+ in the Bi2Sr2
-xLa2-yLnx+yCu2Oz (Ln=Sm, Eu, Gd and Dy) systems. The almost-single ph
ase sample for each system was attained at a limited composition. All
of the sample for each system was semiconducting, and the conduction p
rocess at low temperatures was assumed to be followed by a two-dimensi
onal variable-range hopping. The results after partial substitution of
Pb for Bi and annealing under high-pressure O2 atmosphere are also re
ported.