SYNTHESIS, SPECTROSCOPIC PROPERTIES, AND REACTIVITY OF FERROCENYL(2,4,6-TRI-TERT-BUTYLPHENYL)DIPHOSPHENE

Authors
PIETSCHNIG R NIECKE E
Citation
R. Pietschnig et E. Niecke, SYNTHESIS, SPECTROSCOPIC PROPERTIES, AND REACTIVITY OF FERROCENYL(2,4,6-TRI-TERT-BUTYLPHENYL)DIPHOSPHENE, Organometallics, 15(2), 1996, pp. 891-893
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
2
Year of publication
1996
Pages
891 - 893
Database
ISI
SICI code
0276-7333(1996)15:2<891:SSPARO>2.0.ZU;2-1
Abstract
A ferrocenyl-substituted diphosphene has been synthesized and characte rized, which seems to represent a borderline case concerning the dimer ization of such species. Thus, the tetraphosphetane formed by dimeriza tion readily undergoes cycloreversion to the initial diphosphene upon heating in xylene solution.