CONJUGATE ADDITION OF ORGANOCUPRATES TO DIETHYL VINYLPHOSPHONATE

Authors
BALDWIN IC BECKETT RP WILLIAMS JMJ
Citation
Ic. Baldwin et al., CONJUGATE ADDITION OF ORGANOCUPRATES TO DIETHYL VINYLPHOSPHONATE, Synthesis, (1), 1996, pp. 34
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis → ACNP
ISSN journal
00397881
Issue
1
Year of publication
1996
Database
ISI
SICI code
0039-7881(1996):1<34:CAOOTD>2.0.ZU;2-W
Abstract
The reaction of organocuprate reagents with diethyl vinylphosphonate a ffords the conjugate addition product. The intermediate alpha-metalloa lkylphosphonate can be quenched with electrophiles to afford alpha-sub stituted alkylphosphonates.