KINETIC EVIDENCE FOR PEROXO COMPLEX-FORMATION IN PERBORATE OR HYDROGEN-PEROXIDE OXIDATION OF HEXACYANOFERRATE(II)

Authors
KARUNAKARAN C MUTHUKUMARAN B
Citation
C. Karunakaran et B. Muthukumaran, KINETIC EVIDENCE FOR PEROXO COMPLEX-FORMATION IN PERBORATE OR HYDROGEN-PEROXIDE OXIDATION OF HEXACYANOFERRATE(II), Polish Journal of Chemistry, 70(1), 1996, pp. 79-82
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Polish Journal of Chemistry → ACNP
ISSN journal
01375083
Volume
70
Issue
1
Year of publication
1996
Pages
79 - 82
Database
ISI
SICI code
0137-5083(1996)70:1<79:KEFPCI>2.0.ZU;2-H
Abstract
The oxidation of hexacyanoferrate(II) by perborate or hydrogen peroxid e in the pH range 4.7-7.0 is first order in hexacyanoferrate and is ac id catalyzed. The oxidation exhibits Michaelis-Menten dependence oil p erborate or hydrogen peroxide. Kinetic results provide evidence for co mplex formation between hydrogen peroxide and HFe(CN)(6)(3-).