Ho. Rocha et al., APPLICATION OF PHOTOSENSITIVE SURFACTANT BASED ON NATURAL-RUBBER IN EMULSION POLYMERIZATIONS, Polymer bulletin, 36(2), 1996, pp. 197-202
Photosensitive surfactant was prepared by incorporation of maleic anhy
dride to natural rubber, followed by introduction of cinnamate groups
and neutralization of the remaining carboxylic groups. The surfactant
was used in emulsion polymerization of styrene and acrylic monomers, g
iving rise to stable reactive emulsion. Coated onto HDPE, this emulsio
n lead to solid films which were submitted to UV irradiation.