STRUCTURE OF A BINUCLEAR COPPER(II) COMPLEX WITH BOTH MU-ALKOXO AND MU-FORMATO BRIDGES, [CU2(C17H15N2O3)(HCOO)]

Authors
KAWATA T OHBA S NISHIDA Y TOKII T
Citation
T. Kawata et al., STRUCTURE OF A BINUCLEAR COPPER(II) COMPLEX WITH BOTH MU-ALKOXO AND MU-FORMATO BRIDGES, [CU2(C17H15N2O3)(HCOO)], Acta crystallographica. Section C, Crystal structure communications, 49, 1993, pp. 2070-2072
Citations number
8
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
49
Year of publication
1993
Part
12
Pages
2070 - 2072
Database
ISI
SICI code
0108-2701(1993)49:<2070:SOABCC>2.0.ZU;2-X
Abstract
The crystal structure of a binuclear copper(II) complex, -1:2kappa2O)b is(nitrilomethylidyne)]di-phenolato(3 -)-1kappa2N,O:2kappa2N',O'-dicop per(II), [Cu2-(L-sal)(HCOO)], H-3(L-sal) = N,N'-bis(salicylidene)-1,3- diamino-2-propanol, was determined by X-ray diffraction. The title com pound is ferromagnetic as a result of the roof-shaped structure of the Cu2O(OCO) core (-2J= -94 cm-1). The Cu...Cu distance is 3.260 (1) ang strom and the Cu-O-Cu bond angle is 115.2 (2)-degrees.