STRUCTURE OF A DICHROMIUM OCTACARBONYL COMPLEX OF CYCLOTETRAKIS[BIS(DIISOPROPYL-AMINO)PHOSPHOXANE]

Authors
JASINSKI JP POZDNIAKOV RY WONG EH
Citation
Jp. Jasinski et al., STRUCTURE OF A DICHROMIUM OCTACARBONYL COMPLEX OF CYCLOTETRAKIS[BIS(DIISOPROPYL-AMINO)PHOSPHOXANE], Acta crystallographica. Section C, Crystal structure communications, 49, 1993, pp. 2081-2083
Citations number
11
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
49
Year of publication
1993
Part
12
Pages
2081 - 2083
Database
ISI
SICI code
0108-2701(1993)49:<2081:SOADOC>2.0.ZU;2-B
Abstract
The molecule 2P2,P:2kappa2P6,P8-bis[tetra-carbonylchromium(0)], has an inversion center that relates the two chromium coordination spheres. Each metal atom is cis-coordinated to two P atoms of the tetraphosphox ane ring to form a four-membered Cr-P-O-P chelate ring. The eight-memb ered phosphoxane heterocycle is a novel twist-boat-twist-boat configur ational isomer of the alternative adamantanoid cage. Average distances are Cr-C 1.869 (3), Cr-P 2.337 (4) and P-O 1.65 (2) angstrom.