STRUCTURE OF DI-MU-CHLORO-BIS[(ALLYL ACETATE-O)TRICHLOROTITANIUM(IV)]AT 80-K

Citation
T. Lis et al., STRUCTURE OF DI-MU-CHLORO-BIS[(ALLYL ACETATE-O)TRICHLOROTITANIUM(IV)]AT 80-K, Acta crystallographica. Section C, Crystal structure communications, 49, 1993, pp. 2089-2091
Citations number
7
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
49
Year of publication
1993
Part
12
Pages
2089 - 2091
Database
ISI
SICI code
0108-2701(1993)49:<2089:SODA>2.0.ZU;2-W
Abstract
In the centrosymmetric dimer molecules each of the Ti atoms is bonded to two bridging Cl atoms, three terminal Cl atoms and one carbonyl O a tom of the allyl acetate molecule in a distorted octahedral environmen t with a Ti...Ti distance of 3.851 (4) angstrom. The title crystals ar e isostructural with those of di-mu-chloro-bis[(ethyl acetate)trichlor otitanium(IV)] and di-mu-chloro-bis[(ethyl acetate)trichlorozirconium( IV)].