T. Lis et al., STRUCTURE OF DI-MU-CHLORO-BIS[(ALLYL ACETATE-O)TRICHLOROTITANIUM(IV)]AT 80-K, Acta crystallographica. Section C, Crystal structure communications, 49, 1993, pp. 2089-2091
In the centrosymmetric dimer molecules each of the Ti atoms is bonded
to two bridging Cl atoms, three terminal Cl atoms and one carbonyl O a
tom of the allyl acetate molecule in a distorted octahedral environmen
t with a Ti...Ti distance of 3.851 (4) angstrom. The title crystals ar
e isostructural with those of di-mu-chloro-bis[(ethyl acetate)trichlor
otitanium(IV)] and di-mu-chloro-bis[(ethyl acetate)trichlorozirconium(
IV)].