STRUCTURE OF MONOMERIC [TICL4(HEXAMETHYLPHOSPHORIC TRIAMIDE)2]

Authors
CLEGG W ONEIL PA HENDERSON KW MULVEY RE
Citation
W. Clegg et al., STRUCTURE OF MONOMERIC [TICL4(HEXAMETHYLPHOSPHORIC TRIAMIDE)2], Acta crystallographica. Section C, Crystal structure communications, 49, 1993, pp. 2108-2109
Citations number
10
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
49
Year of publication
1993
Part
12
Pages
2108 - 2109
Database
ISI
SICI code
0108-2701(1993)49:<2108:SOM[T>2.0.ZU;2-Z
Abstract
achlorobis(N,N,N',N',N'',N''-hexamethyl-phosphoric triamide-O)titanium , [TiCl4(hmpa)2], where hmpa is C6H18N3OP, is monomeric and octahedral about the metal centre with the hmpa ligands occupying a trans positi on relative to one another. Both hmpa groups bind to the Ti via their O atoms.