CYCLOADDITION REACTIONS OF METHACRYLOYL ISOCYANATE WITH ARYLIDENEAMINES

Authors
TSUGE O HATTA T MIZUGUCHI R KOBAYASHI T KANZAKI R
Citation
O. Tsuge et al., CYCLOADDITION REACTIONS OF METHACRYLOYL ISOCYANATE WITH ARYLIDENEAMINES, Heterocycles, 42(2), 1996, pp. 533-536
Citations number
4
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Heterocycles → ACNP
ISSN journal
03855414
Volume
42
Issue
2
Year of publication
1996
Pages
533 - 536
Database
ISI
SICI code
0385-5414(1996)42:2<533:CROMIW>2.0.ZU;2-T
Abstract
Arylideneamines (1) added to the acyl isocyanato moiety of methacryloy l isocyanate (MAI) to produce the corresponding [4 + 2] cycloadducts, 2H-1,3,5-oxadiazin-4(3H)-ones (2). It has been clarified that even at low temperature the cycloadducts (2) partially dissociate to two origi nal substrates, MAI and 1, in solution on the basis of VT-nmr spectros copy.