Pulsed probe degenerate four wave mixing experiments were performed on
GaN epilayers using 13 ps pulses at 532 nm. Intensity and time respon
se of the scattering efficiency was studied. Intensity dependence of t
he observed signal suggests carrier generation by both single and two
photon effects. The absolute scattering efficiency was measured and re
lated to pump-induced nonlinear index change. The nonlinear refractive
coefficient found was 1 x 10(-3) cm(2)/GW which is greater than an or
der of magnitude larger than the expected value. Time response of the
signal was found to be dictated by carrier lifetimes. Double-exponenti
al decays to trap levels with lifetimes of 100 ps and 1.1 ns are sugge
sted as the dominant recombination processes. (C) 1996 American Instit
ute of Physics.