X-ray-diffraction data from alkali-metal-doped poly(p-phenylenevinylen
e) (PPV) have been compared with various candidate structures ascertai
ned by Harris [A. B. Harris, Phys. Rev. B 50, 12441 (1994)] in a mean-
field study of a model Hamiltonian which includes polymer-polymer and
guest-host (i.e., alkali-metal-ion to polymer chain) interactions. At
least one of these recently identified phases is found to have a local
ordering motif that is consistent with data from K- and Rb-doped PPV
samples at the highest alkali-metal concentrations. A closely related
structure is found to be consistent with data from Na-doped PPV. These
two structures form a class of channel structures whereby the well-kn
own single alkali-metal-ion array/threefold polymer chain structure is
replaced by a lower symmetry structure characterized by a staggered p
air of parallel quasi-one-dimensional alkali-metal-ion arrays surround
ed by four polymer chains.