J. Stein et al., WEAK FERROMAGNETISM IN THE LOW-TEMPERATURE TETRAGONAL PHASE OF THE CUPRATES, Physical review. B, Condensed matter, 53(2), 1996, pp. 775-784
The criterion for the existence of weak ferromagnetism in the low-temp
erature distorted phases of La2CuO4-type compounds is derived on the b
asis of a general superexchange Hamiltonian. It is found that a ferrom
agnetic canting out of the CuO2 planes is excluded in the pure low-tem
perature tetragonal phase. The anisotropic superexchange interactions
between the copper spins are obtained from a Hubbard model which inclu
des all copper 3d and oxygen 2p orbitals, and all on-site Coulomb matr
ix elements. The results apply when the oxygen octahedra surrounding e
ach copper have tetragonal symmetry. Explicit expressions for the net
ferromagnetic moment and the in-plane and the out-of-plane gaps in the
spin-wave spectrum are derived and estimated in terms of the microsco
pic parameters of the cuprates.