PINATUBO AND PRE-PINATUBO OPTICAL-DEPTH SPECTRA - MAUNA-LOA MEASUREMENTS, COMPARISONS, INFERRED PARTICLE-SIZE DISTRIBUTIONS, RADIATIVE EFFECTS, AND RELATIONSHIP TO LIDAR DATA
Pb. Russell et al., PINATUBO AND PRE-PINATUBO OPTICAL-DEPTH SPECTRA - MAUNA-LOA MEASUREMENTS, COMPARISONS, INFERRED PARTICLE-SIZE DISTRIBUTIONS, RADIATIVE EFFECTS, AND RELATIONSHIP TO LIDAR DATA, JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 98(D12), 1993, pp. 22969-22985
The Ames airborne tracking sunphotometer was operated at the National
Oceanic and Atmospheric Administration (NOAA) Mauna Loa Observatory (M
LO) in 1991 and 1992 along with the NOAA Climate Monitoring and Diagno
stics Laboratory (CMDL) automated tracking sunphotometer and lidar. Ju
ne 1991 measurements provided calibrations, optical-depth spectra, and
intercomparisons under relatively clean conditions; later measurement
s provided spectra and comparisons for the Pinatubo cloud plus calibra
tion checks. June 1991 results are similar to previous MLO springtime
measurements, with midvisible particle optical depth tau(p)(lambda = 0
.526 mum) at the near-background level of 0.012 +/- 0.006 and no signi
ficant wavelength dependence in the measured range (lambda = 0.38 to 1
.06 mum). The arrival of the Pinatubo cloud in July 1991 increased mid
visible particle optical depth by more than an order of magnitude and
changed the spectral shape of tau(p)(lambda) to an approximate power l
aw with an exponent of about -1.4. By early September 1991, the spectr
um was broadly peaked near 0.5 mum, and by July 1992, it was peaked ne
ar 0.8 mum. Our optical-depth spectra include corrections for diffuse
light which increase postvolcanic midvisible tau(p) values by 1 to 3%
(i.e., 0.0015 to 0.0023). NOAA- and Ames Research Center (ARC)-measure
d spectra are in good agreement. Columnar size distributions inverted
from the spectra show that the initial (July 1991) post-Pinatubo cloud
was relatively rich in small particles (r<0.25 mum), which were progr
essively depleted in the August-September 1991 and July 1992 periods.
Conversely, both of the later periods had more of the optically effici
ent medium-sized particles (0.25<r<1 mum) than did the fresh July 1991
cloud. These changes are consistent with particle growth by condensat
ion and coagulation. The effective, or area-weighted, radius increased
from 0.22 +/- 0.06 mum in July 1991 to 0.56 +/- 0.12 mum in August-Se
ptember 1991 and to 0.86 +/- 0.29 mum in July 1992. Corresponding colu
mn mass values were 4.8 +/- 0.7, 9.1 +/- 2.7, and 5.5 +/- 2.0 mug/cm2,
and corresponding column surface areas were 4.4 +/- 0.5, 2.9 +/- 0.2,
and 1.1 +/- 0.1 mum2/cm2. Photometer-inferred column backscatter valu
es agree with those measured by the CMDL lidar on nearby nights. Combi
ning lidar-measured backscatter profiles with photometer-derived backs
catter-to-area ratios gives peak particle areas that could cause rapid
heterogeneous loss of ozone, given sufficiently low particle acidity
and suitable solar zenith angles (achieved at mid- to high latitudes).
Top-of-troposphere radiative forcings for the September 1991 and July
1992 optical depths and size distributions over MLO are about -5 and
-3 W m-2, respectively (hence comparable in magnitude but opposite in
sign to the radiative forcing caused by the increase in manmade greenh
ouse gases since the industrial revolution). Heating rates in the Pina
tubo layer over MLO are 0.55 +/- 0.13 and 0.41 +/- 0.14 K d-1 for Sept
ember 1991 and July 1992, respectively.