ASYMMETRIC DIELS-ALDER REACTION OF ALPHA-SULFINYLACRYLATE DERIVED FROM (1R, 2S, 3R)-3-MERCAPTOCAMPHAN-2-OL

Authors
YANG TK CHEN CJ LEE DS JONG TT JIANG YZ MI AQ
Citation
Tk. Yang et al., ASYMMETRIC DIELS-ALDER REACTION OF ALPHA-SULFINYLACRYLATE DERIVED FROM (1R, 2S, 3R)-3-MERCAPTOCAMPHAN-2-OL, Tetrahedron : asymmetry, 7(1), 1996, pp. 57-60
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
7
Issue
1
Year of publication
1996
Pages
57 - 60
Database
ISI
SICI code
0957-4166(1996)7:1<57:ADROAD>2.0.ZU;2-6
Abstract
The Diels-Alder reaction of cyclopentadiene with a new chiral alpha-su lfinylacrylate, which was prepared from MerCO[(1R, 2S, 3R)-3-mercaptoc amphan-2-ol] at -78 degrees C in the presence of ZnCl2 produced an end o-cycloadduct with 99.4% d.e. in 84% yield.