ENANTIOMERICALLY PURE PALLADACYCLES WITH ONE STEREOGENIC CSP(3) CENTER DIRECTLY BONDED TO THE METAL

Authors
GARCIARUANO JL GONZALEZ AM BARCENA AI CAMAZON MJ NAVARRORANNIGER C
Citation
Jl. Garciaruano et al., ENANTIOMERICALLY PURE PALLADACYCLES WITH ONE STEREOGENIC CSP(3) CENTER DIRECTLY BONDED TO THE METAL, Tetrahedron : asymmetry, 7(1), 1996, pp. 139-148
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
7
Issue
1
Year of publication
1996
Pages
139 - 148
Database
ISI
SICI code
0957-4166(1996)7:1<139:EPPWOS>2.0.ZU;2-M
Abstract
The reaction of homochiral 1-methyl (ethyl and phenyl)-2-p-tolylsulfin yl ethanones with Pd(OAc)(2)/AcOH yield enantiomerically pure trimer o rthopalladated compounds containing a stereogenic carbon C-sp(3) direc tly joined to the Pd atom.