REACTION OF ALCOHOLS WITH ALPHA-OXIDES CATALYZED BY ALUMINUM AND TITANIUM ALCOHOLATE COMPLEXES OF BORON-TRIFLUORIDE ETHERATE .1. REACTION-PRODUCT COMPOSITION

Authors
GUREVICH MA GUSKOV AK MAKAROV MG SUCHKOV YP SHVETS VF
Citation
Ma. Gurevich et al., REACTION OF ALCOHOLS WITH ALPHA-OXIDES CATALYZED BY ALUMINUM AND TITANIUM ALCOHOLATE COMPLEXES OF BORON-TRIFLUORIDE ETHERATE .1. REACTION-PRODUCT COMPOSITION, Kinetics and catalysis, 36(6), 1995, pp. 785-787
Citations number
9
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
36
Issue
6
Year of publication
1995
Pages
785 - 787
Database
ISI
SICI code
0023-1584(1995)36:6<785:ROAWAC>2.0.ZU;2-S
Abstract
The composition of the products formed in the reaction between primary aliphatic alcohols and ethylene oxide was studied in the presence of catalytic systems based on boron trifluoride and aluminum and titanium alkoxides. It was shown that the distribution coefficient for the cat alytic system under study was less than that for the catalysts used pr eviously. Distribution coefficients for the products of oxyethylation were calculated.