SILYL-SUBSTITUTED CYCLOPROPYL CARBENOIDS

Authors
CREARY X JIANG ZQ BUTCHKO M MCLEAN K
Citation
X. Creary et al., SILYL-SUBSTITUTED CYCLOPROPYL CARBENOIDS, Tetrahedron letters, 37(5), 1996, pp. 579-582
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
5
Year of publication
1996
Pages
579 - 582
Database
ISI
SICI code
0040-4039(1996)37:5<579:SCC>2.0.ZU;2-9
Abstract
Cyclopropyl carbeniods, generated from dibromocyclopropanes and methyl lithium, insert preferentially into SiMe(3) activated C-H bonds. In ot her cases, allene formation remains the dominant process.