CONVERSION OF (1-HETERODIENE)TRICARBONYLIRON(0) COMPLEXES INTO (2-AMINOHOMODIENE)TRICARBONYLIRON(0) COMPLEXES

Authors
ACKLAND MJ DANKS TN HOWELLS ME
Citation
Mj. Ackland et al., CONVERSION OF (1-HETERODIENE)TRICARBONYLIRON(0) COMPLEXES INTO (2-AMINOHOMODIENE)TRICARBONYLIRON(0) COMPLEXES, Tetrahedron letters, 37(5), 1996, pp. 691-694
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
5
Year of publication
1996
Pages
691 - 694
Database
ISI
SICI code
0040-4039(1996)37:5<691:CO(CI(>2.0.ZU;2-9
Abstract
Treatment of (1-azadiene)tricarlonyliron(0) complex 1 with lithiated a mines leads to attack at a metal carbonyl and the formation of formami des, whereas complexes 2 and 3 undergo deprotonation of the methyl gro up at C-2 followed by a rearrangement to form (2-aminohomodiene)tricar bonyliron(0) complexes 8 or 10 in good yield.