ARYL DIAZINYL KETOXIMES - SYNTHESIS AND CONFIGURATIONAL ASSIGNMENT

Citation
G. Heinisch et al., ARYL DIAZINYL KETOXIMES - SYNTHESIS AND CONFIGURATIONAL ASSIGNMENT, Heterocycles, 43(1), 1996, pp. 151-172
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
03855414
Volume
43
Issue
1
Year of publication
1996
Pages
151 - 172
Database
ISI
SICI code
0385-5414(1996)43:1<151:ADK-SA>2.0.ZU;2-H
Abstract
Preparation of a series of new aryl diazinyl ketoximes (7a,b - 12a,b) required as synthetic building blocks is described. Separation of the E/Z-isomers obtained was achieved by means of chromatography, their co nfiguration was assigned using nmr techniques. Moreover, procedures fo r the synthesis of the starting ketones (1b - 6b) are given.