CRYSTAL-STRUCTURE OF DICARBONYL(ETA(5)-CYCLOPENTADIENYL) (TRIPHENYLPHOSPHINE)IRON HEXAFLUOROPHOSPHATE, [(ETA(5)-C5H5)FE(CO)(2)(PPH(3))(-]()][PF6)

Citation
Ts. Janik et al., CRYSTAL-STRUCTURE OF DICARBONYL(ETA(5)-CYCLOPENTADIENYL) (TRIPHENYLPHOSPHINE)IRON HEXAFLUOROPHOSPHATE, [(ETA(5)-C5H5)FE(CO)(2)(PPH(3))(-]()][PF6), Journal of chemical crystallography, 25(11), 1995, pp. 751-754
Citations number
7
Categorie Soggetti
Crystallography,Spectroscopy
ISSN journal
10741542
Volume
25
Issue
11
Year of publication
1995
Pages
751 - 754
Database
ISI
SICI code
1074-1542(1995)25:11<751:COD(>2.0.ZU;2-E
Abstract
The title compound crystallizes in the centrosymmetric triclinic space group P (l) over bar (No. 2) with a = 10.818(1)Angstrom b = 10.876(1) Angstrom, c 11.072(2)Angstrom, alpha = 98.74(1)degrees, beta = 98.83(1 )degrees, gamma = 96.61(1)degrees, V = 1259.6(3)Angstrom(3) and Z = 2. Interatomic distances include Fe-P = 2.243(2)Angstrom, Fe-CO= 1.771(6 )-1.781(5)Angstrom Fe-C(C5H5) = 2.074(6)-2.103(5)Angstrom and P-F = 1. 511(6)1.571(4)Angstrom.