Spin-polarized fragments B-14 and B-15 produced in intermediate-energy
projectile fragmentation reactions were implanted in a Mg single crys
tal, and the electric quadrupole moments Q for B-14 and B-15 were dete
rmined by beta-NMR spectroscopy. The results, \Q(B-14)\ = 29.84 +/- 0.
75 mb and \Q(B-15)\ = 38.01 +/- 1.08 mb, are compared with theoretical
models. Shell-model calculations with 0 (h) over bar omega model spac
e, using effective charges commonly accepted in this mass region, pred
ict values about 40 % larger than the experimental Q(B-15). Agreement
is obtained when a much smaller effective charge for neutrons is emplo
yed. The Q(B-14) sensitively reflects small admixture of the d(3/2) ne
utron configuration and, when combined with the previously obtained da
ta for the magnetic moment, determines reliably the ground state wave
function of B-14.