E. Acosta et al., INDUCED ELECTRIC BIREFRINGENCE AND VISCOSITY STUDIES IN MICROEMULSIONS, Colloids and surfaces. A, Physicochemical and engineering aspects, 106(1), 1996, pp. 11-21
The Kerr constant was determined for the AOT-water-dodecane water-in-o
il microemulsion. The goal of these experiments has been to test the v
alidity of the theoretical approach of van der Linden, S. Geiger and D
. Bedaux, Phys. A., 156 (1989) 130, which explains the electro-optical
process through an elastic deformation of the droplets. The bending m
odulus of the curved surfactant monolayer along different paths of the
phase diagram was measured. It was concluded that for concentrations
relatively far from phase transition regions the theory can account fo
r the experimental results. However, we have measured the Kerr constan
t, relaxation times and viscosity in microemulsion-based (gelatin) gel
s. These magnitudes have been measured as a function of gelatin concen
tration. For low biopolymer concentrations, Kerr constants do not vary
too much, whereas in a certain concentration range (about 3-4%), they
increase abruptly. This behaviour is similar to those of electric con
ductivity and viscosity. We have estimated the characteristic size of
anisotropic microstructures. The possibility of the presence of a bran
ched structure has been analysed by using a stretched-exponents approa
ch proposed by M. Daoud and J. Klafter, J. Phys. A: Math. Nucl. Gen.,
23 (1990) L981.