INDUCED ELECTRIC BIREFRINGENCE AND VISCOSITY STUDIES IN MICROEMULSIONS

Citation
E. Acosta et al., INDUCED ELECTRIC BIREFRINGENCE AND VISCOSITY STUDIES IN MICROEMULSIONS, Colloids and surfaces. A, Physicochemical and engineering aspects, 106(1), 1996, pp. 11-21
Citations number
27
Categorie Soggetti
Chemistry Physical
ISSN journal
09277757
Volume
106
Issue
1
Year of publication
1996
Pages
11 - 21
Database
ISI
SICI code
0927-7757(1996)106:1<11:IEBAVS>2.0.ZU;2-W
Abstract
The Kerr constant was determined for the AOT-water-dodecane water-in-o il microemulsion. The goal of these experiments has been to test the v alidity of the theoretical approach of van der Linden, S. Geiger and D . Bedaux, Phys. A., 156 (1989) 130, which explains the electro-optical process through an elastic deformation of the droplets. The bending m odulus of the curved surfactant monolayer along different paths of the phase diagram was measured. It was concluded that for concentrations relatively far from phase transition regions the theory can account fo r the experimental results. However, we have measured the Kerr constan t, relaxation times and viscosity in microemulsion-based (gelatin) gel s. These magnitudes have been measured as a function of gelatin concen tration. For low biopolymer concentrations, Kerr constants do not vary too much, whereas in a certain concentration range (about 3-4%), they increase abruptly. This behaviour is similar to those of electric con ductivity and viscosity. We have estimated the characteristic size of anisotropic microstructures. The possibility of the presence of a bran ched structure has been analysed by using a stretched-exponents approa ch proposed by M. Daoud and J. Klafter, J. Phys. A: Math. Nucl. Gen., 23 (1990) L981.