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TOWARDS THE SYNTHESIS OF AMINODIBENZO[B,E][1,4]DIOXIN DERIVATIVES VIACATIONIC RUTHENIUM COMPLEXES

Authors

CAMBIE RC CLARK GR COOMBE SL COULSON SA RUTLEDGE PS WOODGATE PD

Citation

Rc. Cambie et al., TOWARDS THE SYNTHESIS OF AMINODIBENZO[B,E][1,4]DIOXIN DERIVATIVES VIACATIONIC RUTHENIUM COMPLEXES, Journal of organometallic chemistry, 507(1-2), 1996, pp. 1-21

Citations number

Categorie Soggetti

Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear

Journal title

Journal of organometallic chemistry → ACNP

ISSN journal

0022328X

Volume

507

Issue

1-2

Year of publication

1996

Pages

1 - 21

Database

ISI

SICI code

0022-328X(1996)507:1-2<1:TTSOAD>2.0.ZU;2-R

Abstract

Double nucleophilic aromatic substitution reactions between N-substitu ted (eta(6)-1,2-dichlorobenzene)RuCp(+) salts and substituted 1,2-benz enediols have been carried out under mild conditions to prepare N-subs tituted (eta(6)-dibenzo[b,e][1,4]dioxin)ruthenium(II) complexes. The d ibenzodioxin ligands were subsequently liberated by photolysis, with r adiation from a sunlamp or from a medium pressure Hg lamp (300 nm).