BIS(L,4BIS(TRIMETHYLSILYL) BUTA-1,3-DIENE) COBALT - SYNTHESIS AND MOLECULAR-STRUCTURE

Authors
CLOKE FGN GARDINER MG RASTON CL SIMPSON SJ
Citation
Fgn. Cloke et al., BIS(L,4BIS(TRIMETHYLSILYL) BUTA-1,3-DIENE) COBALT - SYNTHESIS AND MOLECULAR-STRUCTURE, Journal of organometallic chemistry, 507(1-2), 1996, pp. 245-248
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
507
Issue
1-2
Year of publication
1996
Pages
245 - 248
Database
ISI
SICI code
0022-328X(1996)507:1-2<245:BBC-SA>2.0.ZU;2-F
Abstract
Co-condensation of cobalt atoms with an excess of (E,E)-1,4-bis(trimet hylsilyl)buta-1,3-diene in hexane at -196 degrees C yields the homolep tic bis(butadiene) complex [Co{eta-C4H4(SiMe(3))(2)}(2)] (1) as the so le volatile product. Compound 1 was characterized by H-1 NMR and EPR s pectroscopy, mass spectrometry and a single-crystal X-ray structure de termination.