2,2'-BIS(DIPHENYLPHOSPHINO) BIPHENYL REVISITED

Authors
DESPONDS O SCHLOSSER M
Citation
O. Desponds et M. Schlosser, 2,2'-BIS(DIPHENYLPHOSPHINO) BIPHENYL REVISITED, Journal of organometallic chemistry, 507(1-2), 1996, pp. 257-261
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
507
Issue
1-2
Year of publication
1996
Pages
257 - 261
Database
ISI
SICI code
0022-328X(1996)507:1-2<257:2BR>2.0.ZU;2-D
Abstract
The reaction between 2,2'-dilithiobiphenyl and two equivalents of chlo rodiphenylphosphine is confirmed to afford equal amounts of 9-phenyl-9 -phosphafluorene (2) and triphenylphosphine. 2,2'-Bis(diphenylphosphin o)biphenyl (1,1'-biphenyl-2,2'-diylbis(diphenylphos phine) (1)) can be conveniently prepared by Ullmann coupling of 2-iodophenyldiphenylphos phine oxide and subsequent reduction with trichlorosilane.