THEORY OF THE LOW-FREQUENCY ELECTROROTATION OF POLYSTYRENE PARTICLES IN ELECTROLYTE SOLUTION

Citation
C. Grosse et Vn. Shilov, THEORY OF THE LOW-FREQUENCY ELECTROROTATION OF POLYSTYRENE PARTICLES IN ELECTROLYTE SOLUTION, Journal of physical chemistry, 100(5), 1996, pp. 1771-1778
Citations number
20
Categorie Soggetti
Chemistry Physical
ISSN journal
00223654
Volume
100
Issue
5
Year of publication
1996
Pages
1771 - 1778
Database
ISI
SICI code
0022-3654(1996)100:5<1771:TOTLEO>2.0.ZU;2-5
Abstract
An interpretation is given for the cofield rotation observed in low-fr equency electrorotation experiments using polystyrene particles in ele ctrolyte solution. It is shown that the main cause of the particle rot ation is the electroosmotic velocity of the electrolyte inside the thi n double layer, rather than the torque exerted by the rotating electri c field on the out of phase part of the induced dipole moment.