PYRAMIDAL TELLURITE IONS TE(N(T)BU)(2)(E(T)BU)(-)(E=0,NH) - SYNTHESESAND STRUCTURES OF [K(THF)TE(N(T)BU)(2)(O(T)BU)](2) AND ([LITE(N(T)BU)(2)(NH(T)BU)]2LICL)(2)

Authors
CHIVERS T GAO XL PARVEZ M
Citation
T. Chivers et al., PYRAMIDAL TELLURITE IONS TE(N(T)BU)(2)(E(T)BU)(-)(E=0,NH) - SYNTHESESAND STRUCTURES OF [K(THF)TE(N(T)BU)(2)(O(T)BU)](2) AND ([LITE(N(T)BU)(2)(NH(T)BU)]2LICL)(2), Inorganic chemistry, 35(3), 1996, pp. 553
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
35
Issue
3
Year of publication
1996
Database
ISI
SICI code
0020-1669(1996)35:3<553:PTIT-S>2.0.ZU;2-2
Abstract
The isoelectronic, pyramidal tellurite anions Te(N(t)Bu)(2)(E(t)Bu)(-) (E = O, NH) have been structurally characterized in the centrosymmetr ic dimers [K(THF)-Te(N(t)Bu)(2)(O(t)Bu)](2) 3 . 2THF, and {[LiTe(N(t)B u)(2)(NHt-Bu)]2LiCl}(2), 4, respectively. Complex 3 is prepared by the reaction of (t)BuNTe(mu-N(t)Bu)(2)TeN(t)Bu with KOt-Bu in toluene, wh ile 4 is formed by the treatment of [Li2Te(N(t)Bu)(3)](2) with HCl gas .