PREPARATION, STRUCTURE, AND PROPERTIES OF AN ANIONIC TETRAMERIC COPPER COMPLEX CONTAINING A PLANAR, 8-MEMBERED RING CORE

Authors
PULLEN AE PIOTRASCHKE J ABBOUD KA REYNOLDS JR
Citation
Ae. Pullen et al., PREPARATION, STRUCTURE, AND PROPERTIES OF AN ANIONIC TETRAMERIC COPPER COMPLEX CONTAINING A PLANAR, 8-MEMBERED RING CORE, Inorganic chemistry, 35(3), 1996, pp. 793
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
35
Issue
3
Year of publication
1996
Database
ISI
SICI code
0020-1669(1996)35:3<793:PSAPOA>2.0.ZU;2-3
Abstract
The three-solvent reaction of (Bu(4)N)(2)[Zn(dmt)(2)] (dmt = C3S52- = 3-thioxo-1,2-dithiole-4,5-dithiolato) (CH2-Cl2), (Et(4)N)(2)tto (tto = C2S42- = tetrathiooxalate) (H2O), and CuCl2 . 2H(2)O (CH3OH) yields t he anionic tetrameric copper complex (Bu(4)N)(2)[Cu(dmt)](4). The dian ion contains a planar, eight-membered ring core of four Cu atoms and f our S atoms. The dmt ligand coordinates for the first time in this par ticular fashion.