USE OF DISULFIDE OIL IN THE HIGH-TEMPERATURE SYNTHESIS OF HETEROCYCLIC-COMPOUNDS

Authors
DERYAGINA EN KORCHEVIN NA SUKHOMAZOVA EN RUSSAVSKAYA NV LEVANOVA YP
Citation
En. Deryagina et al., USE OF DISULFIDE OIL IN THE HIGH-TEMPERATURE SYNTHESIS OF HETEROCYCLIC-COMPOUNDS, Petroleum chemistry, 35(5), 1995, pp. 457-462
Citations number
12
Categorie Soggetti
Energy & Fuels","Engineering, Chemical","Engineering, Petroleum
Journal title
Petroleum chemistry → ACNP
ISSN journal
09655441
Volume
35
Issue
5
Year of publication
1995
Pages
457 - 462
Database
ISI
SICI code
0965-5441(1995)35:5<457:UODOIT>2.0.ZU;2-3
Abstract
The pyrolysis of dimethyl and diethyl disulphides and ''disulphide oil '' (a waste product of oil refining) was carried out at 580-610 degree s C. On the basis of the gas-phase reaction of ''disulphide oil'' with the chlorobenzene-acetylene system or 2-chlorothiophene-acetylene sys tem, new methods have been developed for the simultaneous production o f thiophene and benzothiophene or thiophene and thienothiophene in hig h yields. The mechanism of the reactions studied are discussed.