PHOTOLYSIS OF CF3NO AS A SOURCE OF CF3 RADICALS, RATE-CONSTANT OF THECF3+CF3NO REACTION AT 296 K

Authors
GARMANOV AB VAKHTIN AB
Citation
Ab. Garmanov et Ab. Vakhtin, PHOTOLYSIS OF CF3NO AS A SOURCE OF CF3 RADICALS, RATE-CONSTANT OF THECF3+CF3NO REACTION AT 296 K, International journal of chemical kinetics, 28(2), 1996, pp. 71-77
Citations number
28
Categorie Soggetti
Chemistry Physical
Journal title
International journal of chemical kinetics → ACNP
ISSN journal
05388066
Volume
28
Issue
2
Year of publication
1996
Pages
71 - 77
Database
ISI
SICI code
0538-8066(1996)28:2<71:POCAAS>2.0.ZU;2-A
Abstract
The linear absorption cross-sections and photodissociation quantum yie lds for CF3NO have been measured at the wavelengths 694.3 and 632.8 nm (ruby and He-Ne lasers, respectively) in a wide range of total pressu re at T = 296 K. The secondary reactions following the photolysis of C F3NO have been studied. The rate constant of the CF3 + CF3NO reaction has been measured. The results obtained show CF3NO photolysis be a con venient source of CF3 radicals For kinetic studies. (C) 1996 John Wile y & Sons, Inc