Ab. Garmanov et Ab. Vakhtin, PHOTOLYSIS OF CF3NO AS A SOURCE OF CF3 RADICALS, RATE-CONSTANT OF THECF3+CF3NO REACTION AT 296 K, International journal of chemical kinetics, 28(2), 1996, pp. 71-77
The linear absorption cross-sections and photodissociation quantum yie
lds for CF3NO have been measured at the wavelengths 694.3 and 632.8 nm
(ruby and He-Ne lasers, respectively) in a wide range of total pressu
re at T = 296 K. The secondary reactions following the photolysis of C
F3NO have been studied. The rate constant of the CF3 + CF3NO reaction
has been measured. The results obtained show CF3NO photolysis be a con
venient source of CF3 radicals For kinetic studies. (C) 1996 John Wile
y & Sons, Inc