NUCLEOPHILIC-ADDITION OF TRIETHYL PHOSPHITE TO ACETATES OF THE BAYLIS-HILLMAN ADDUCTS - STEREOSELECTIVE SYNTHESIS OF (E)-ALLYLPHOSPHONATES AND (Z)-ALLYLPHOSPHONATES

Authors
BASAVAIAH D PANDIARAJU S
Citation
D. Basavaiah et S. Pandiaraju, NUCLEOPHILIC-ADDITION OF TRIETHYL PHOSPHITE TO ACETATES OF THE BAYLIS-HILLMAN ADDUCTS - STEREOSELECTIVE SYNTHESIS OF (E)-ALLYLPHOSPHONATES AND (Z)-ALLYLPHOSPHONATES, Tetrahedron, 52(6), 1996, pp. 2261-2268
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
52
Issue
6
Year of publication
1996
Pages
2261 - 2268
Database
ISI
SICI code
0040-4020(1996)52:6<2261:NOTPTA>2.0.ZU;2-J
Abstract
Nucleophilic addition of triethyl phosphite to 3-acetoxy-2-methyleneal kanenitriles and methyl 3-acetoxy-2-methylenealkanoates provides (2E)- 2-(diethoxyphosphorylmethyl)alk-2-enenitriles and methyl (2Z)-2-(dieth oxyphosphorylmethyl) alk-2-enoates respectively with good stereoselect ivity.