PRECISE LEAD-ISOTOPE FINGERPRINTING OF HYDROTHERMAL ACTIVITY ASSOCIATED WITH ORDOVICIAN TO CARBONIFEROUS METALLOGENIC EVENTS IN THE LACHLANFOLD BELT OF NEW-SOUTH-WALES
Gr. Carr et al., PRECISE LEAD-ISOTOPE FINGERPRINTING OF HYDROTHERMAL ACTIVITY ASSOCIATED WITH ORDOVICIAN TO CARBONIFEROUS METALLOGENIC EVENTS IN THE LACHLANFOLD BELT OF NEW-SOUTH-WALES, Economic geology and the bulletin of the Society of Economic Geologists, 90(6), 1995, pp. 1467-1505
The Pb isotope signatures of sulfide mineralization within the Lachlan
fold belt can be divided into those containing almost exclusively man
tle-derived Pb, those containing Pb which has had a long crustal resid
ence time, and those containing Pb of mixed mantle and crust parentage
. In the Early Paleozoic (Ordovician to Silurian) all the major and th
e majority of other deposits have either crust or mantle signatures wi
th very little evidence of mixing. Porphyry to epithermal Cu and/or Au
mineralization hosted within Ordovician shoshonitic rocks (eg., the G
oonumbla deposits) have a wide range of Pb-206/Pb-204 ratios (17.68 -
18.21) and very low Pb-207/Pb-204 (15.40 - 15.49) and Pb-208/Pb-204 (3
7.21 - 37.83) ratios. Ores and their corresponding host rocks have ver
y similar isotopic compositions suggesting that Pb is magmatic in orig
in. On Pb-208/Pb-204 vs. Pb-206/Pb-204 and Pb-207/Pb-204 vs. Pb-206/Pb
-204 diagrams, these data plot on very precise lines (mantle mixing li
nes) which represent mixing of Pb from two or more mantle reservoirs.
It is postulated that the position of each deposit along this line is
an indication of the timing of metallogenesis within the Ordovician ma
gmatic cycle and possibly also the degree of mixing of melts derived f
rom a more primitive asthenosphere and a more enriched lithosphere, po
tentially fertile for Cu and Au. Exploration samples which plot on the
mantle mixing lines and have high Pb-206/Pb-204 ratios are considered
to have the best chance of representing a large metallogenic event. D
eposits which are spatially related to Ordovician volcanics but which
have more crustlike Pb isotope signatures and are generally relatively
small in size, are considered to have formed in response to younger (
Silurian? to Devonian) magmatic or metamorphic events which have recyc
led Pb from the Ordovician rocks and mixed it with crustal Pb. Volcani
c-hosted massive sulfide mineralization has a very restricted range of
Pb isotope ratios (Pb-206/Pb-204 = 18.03 - 18.11; Pb-207/Pb-204 = 15.
56 - 15.63; Pb-208/Pb-204 = 37.95 - 38.22), with the largest deposits
containing Pb with strong crustal affinities. With rare exceptions, bo
th large and small deposits contain very homogeneous Pb isotope ratios
, although in the large Woodlawn deposit there is evidence of more tha
n one data population, indicative of superimposed hydrothermal activit
y. The overall range of Pb-206/Pb-204 ratios for the volcanic-hosted m
assive sulfide deposits results from mixing of a less radiogenic crust
al Pb, represented by the Currawang deposit hosted in pillow basalts,
and a more radiogenic component, represented by the Woodlawn deposit,
hosted in more felsic volcanic and volcaniclastic rocks. The range of
Pb-207/Pb-204 and Pb-208/Pb-204 ratios results from mixing of crustal-
dominated Pb with Pb derived from rocks with a mantle heritage, princi
pally Ordovician magmatic units. Evidence of such mixing, which may be
due to hydrothermal or magmatic processes, is concentrated along the
boundaries of the Silurian volcanic terranes adjacent to the Ordovicia
n units. Deposits which show evidence of incorporation of mantle Pb al
so tend to have higher Au concentrations. Metallogenesis in the Devoni
an and Carboniferous is dominantly related to granitoid intrusion, alt
hough some sediment-hosted base metal mineralization and epithermal Au
mineralization is probably related to comagmatic volcanism. The Pb in
the intrusion-related mineralization is isotopically very similar to
magmatic Pb, with very little evidence of hydrothermal mixing with int
ruded host or wall rocks. The Carboniferous mineralization shows great
er evidence of incorporation of mantle Pb. A plumbo-tectonic model for
the Lachlan fold belt based on mixing isochrons between a crustal end
member growth curve and a mantle end-member growth curve yields miner
alization model ages for the Paleozoic with a precision generally bett
er than +/- 15 m.y. The Lachlan fold belt crustal growth curve is a mo
dified last stage to the Cumming and Richards (1975) global crustal gr
owth curve. It is defined by a mu of 13.3 and passes through the avera
ge values for the Woodlawn Zn-Pb mineralization (Pb-206/Pb-204 = 18.09
0, Pb-207/Pb-204 = 15.610, Pb-208/Pb-204 = 38.118) at an age of 420 Ma
. The mantle curve has a mu of 10 and passes through the Goonumbla ore
body data (Pb-206/Pb-204 = 18.204, Pb-207/Pb-204 = 15.487, Pb-208/Pb-2
04 = 37.831) at an age of 440 Ma. The points of intersection of these
curves with the respective global curves are as yet unclear due to the
dearth of ore Pb isotope data in the Upper Proterozoic. The model als
o appears to be valid for older (Kanmantoo fold belt) and younger (New
England orogen) units of the Tasman fold belt system. The relatively
high precision of the model is an indication of the presence of Paleoz
oic and Upper Proterozoic source regions which have homogeneous Pb iso
tope compositions and U/Pb and Th/U ratios.