THE REACTIONS OF CYCLOPROPENE COMPOUNDS W ITH ELECTROPHILIC REAGENTS

Citation
Vr. Kartashov et al., THE REACTIONS OF CYCLOPROPENE COMPOUNDS W ITH ELECTROPHILIC REAGENTS, Uspehi himii, 62(10), 1993, pp. 991-1006
Citations number
120
Categorie Soggetti
Chemistry
Journal title
ISSN journal
00421308
Volume
62
Issue
10
Year of publication
1993
Pages
991 - 1006
Database
ISI
SICI code
0042-1308(1993)62:10<991:TROCCW>2.0.ZU;2-F
Abstract
Data on the reactions of cyclopropene compounds with acids, halogen- a nd sulfur-containing electrophilic reagents, mercury salts are systema tized. The influence of electrophile nature and structure of cycloprop ene derivatives on the processes of remaining and opening ring, the st ereochemistry of reagents addition to cyclopropene bond and formation of ring opening products are reviewed. Mechanism of reactions are disc ussed.