The formation of composite ferrocyanide adsorbents prepared on the bas
is of clinoptilolite is studied by potentiometric titration, X-ray dif
fraction analysis, and IR spectroscopy, and the nature of ion-exchangi
ng complex is established. Exchange capacity, selectivity, and hydroly
tic stability of the sorbents are characterized. Distribution coeffici
ents with modified samples can be as large as 10 000 for Cs-137; howev
er, with increase of the background salt concentration above 0.17 g 1(
-1), competing ions have noticeable effect on the adsorption propertie
s of the aluminosilicates.