FORCED FORWARD SMOLDER COMBUSTION

We consider porous cylindrical samples closed to the surrounding envir onment except at the ends, with gas forced into the sample through one of the ends. A smolder wave is initiated at that end and propagates i n the same direction as the flow of the gas. We employ asymptotic meth ods to find smolder wave solutions with two different structures. Each structure has two interior layers, i.e., regions of relatively rapid variation in temperature separated by longer regions in which the temp erature is essentially constant. One layer is that of the combustion r eaction, while the other is due to heat transfer between the solid and the gas. The layers propagate with constant, though not necessarily t he same, velocity, and are separated by a region of constant high temp erature. A so-called reaction leading wave structure occurs when the v elocity of the combustion layer exceeds that of the heat transfer laye r, while a so-called reaction trailing wave structure is obtained when the combustion layer is slower than the heat transfer layer. The form er (latter) occurs when the incoming oxygen concentration is sufficien tly high (low). Reaction trailing structures allow for the possibility of quenching if the gas mass influx is large enough; that is, incompl ete conversion can occur due to cooling of the reaction by the incomin g gas. For each wave structure there exist stoichiometric, and kinetic ally controlled solutions in which the smolder velocity is determined, respectively, by the rate of oxygen supply to the reaction site and b y the rate of consumption in the reaction, i.e., by the kinetic rate. Stoichiometric (kinetically controlled) solutions occur when the incom ing gas flux is sufficiently low (high). For each of the four solution types, we determine analytical expressions for the propagation veloci ties of the two layers, the burning temperature, and the final degree of solid conversion. We also determine analytical expressions for the spatial profiles of temperature, gas flux, and oxygen concentration. G ravitational forces are considered and are shown to have a minimal eff ect provided the ambient pressure is large compared to the hydrostatic pressure drop. The solutions obtained provide qualitative theoretical descriptions of various experimental observations of forward smolder. In particular, the reaction trailing stoichiometric solution correspo nds to the experimental observations of Ohlemiller and Lucca, while th e reaction leading stoichiometric solution corresponds to the experime ntal observations of Torero et al.